As we have seen in a previous article,
the emission spectra of different elements contain discrete lines. The
following image shows the visible region of the emission spectra for
hydrogen.
The
quantized emission spectra indicated to Bohr that perhaps electrons
could only exist within the atom at certain atomic radii and energies.
Recall that quantized
refers to the fact that energy can only be absorbed and emitted in a
range of allowable values rather than with any possible value. The
following diagram of the Bohr model shows the electron existing in a
finite number of allowed orbits or shells around the nucleus.
From
this model, Bohr derived an equation that correctly predicted the
various energy levels in the hydrogen atom, which corresponded directly
to the emission lines in the hydrogen spectrum. Bohr's model was also
successful at predicting the energy levels in other one-electron
systems, such as He+. However, it failed to explain the electronic structure in atoms that contained more than one electron.
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