The Bohr model worked beautifully for explaining the hydrogen atom and other single electron systems such as He+.
Unfortunately, it did not do as well when applied to the spectra of
more complex atoms. Furthermore, the Bohr model had no way of explaining
why some lines are more intense than others or why some spectral lines
split into multiple lines in the presence of a magnetic field—the Zeeman
effect.
In
the following decades, work by scientists such as Erwin Schrödinger
showed that electrons can be thought of as behaving like waves and
behaving as particles. This means that it is not possible to know both a
given electron’s position in space and its velocity at the same time, a
concept that is more precisely stated in Heisenberg's uncertainty principle.
The uncertainty principle contradicts Bohr’s idea of electrons existing
in specific orbits with a known velocity and radius. Instead, we can
only calculate probabilities of finding electrons in a particular region of space around the nucleus.
The
modern quantum mechanical model may sound like a huge leap from the
Bohr model, but the key idea is the same: classical physics is not
sufficient to explain all phenomena on an atomic level. Bohr was the
first to recognize this by incorporating the idea of quantization into
the electronic structure of the hydrogen atom, and he was able to
thereby explain the emission spectra of hydrogen as well as other
one-electron systems.
No comments:
Post a Comment